Common multi-word phrases that nearly rhyme with immaterial:

5 syllables:
brick material,
bridge material,
bring material,
drill material,
his material,
in material,
is material,
pitch material,
sheer material,
spring material,
stiff material,
strip material,
thick material,
thing material,
this material,
which material,
with material,
some material,
bridge materials,
bring materials,
brings material,
drift material,
drill materials,
filled material,
flint material,
his materials,
its material,
pitch materials,
print material,
script material,
since material,
sized material,
spilled material,
spring materials,
stiff materials,
thick materials,
things material,
which materials,
with materials,
by material,
check material,
chief material,
dream material,
dredge material,
dutch material

6 syllables:
adding material,
arousing material,
clear material,
resin material,
submit material,
virgin material,
viscid material,
become material,
extra material,
adding materials,
career materials,
classic material,
drawing material,
drying material,
enriched material,
filler material,
flowing material,
gritty material,
growing material,
inner material,
issue material,
jewish material,
keying material,
litter material,
prism material,
reprint material,
resin materials,
resist material,
richer material,
sewing material,
sticky material,
stiffer material,
submit materials,
their material,
thicker material,
thinner material,
tissue material,
tying material,
viewing material,
virgin materials,
access material,
added material,
algal material,
became material,
enjoy material

7 syllables:
adhering material,
consider material,
decaying material,
deliver material,
emitter material,
offering material,
pursuing material,
reviewing material,
supplying material,
transferring material

Some other possibilities:

What's up with this "phrase rhymes" section?

This experimental new tab on RhymeZone shows you phrases that might be good matches for your multi-syllable query word. For example, the word poetry produces phrase rhymes like boba tea and swollen knee and hopeful he and moments we. Some of these (like "boba tea") are single conceptual units, while others (like "hopeful he") are sentence fragments. Both kinds of results may be useful when writing slant rhymes that cross line boundaries, which are popular in hip hop lyrics and musical theater. Typically, RhymeZone's phrase rhymes are assonant (share vowel sounds) with the query word, with some degree of consonant match as well.

You'll often find lots of options in this tab, including many junky ones that don't work well. Stay tuned while we find the right formula!

Commonly used words are shown in bold. Rare words are dimmed.
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See immaterial used in context: 2 rhymes, 1 Shakespeare work, several books and articles.

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